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Antioxidants is a class of chemical additives used to inhibit or delay the oxidative degradation of materials, mainly through the blocking of free radical chain reaction, decomposition of peroxides or passivation of metal ions and other ways to play a role. In the chemical industry, antioxidants are indispensable functional additives in polymer materials (plastics, rubber, fibers), lubricants, fuels and industrial chemicals, which can significantly extend the service life of the materials and improve product stability.
Antioxidant Name | Type | CAS No. | Molecular Weight (g/mol) | Appearance | Melting Point (°C) | Solubility | Key Features | Recommended Dosage |
Antioxidant 1010 | Hindered Phenol | 6683-19-8 | 1177.65 | White crystalline powder | 110-125 | Soluble in acetone, chloroform | High-temperature resistance (≤300°C), low volatility | 0.1%-0.5% |
Antioxidant 168 | Phosphite | 31570-04-4 | 646.93 | White powder | 180-185 | Soluble in toluene, dichloromethane | Secondary antioxidant, decomposes peroxides, prevents yellowing | 1:1 ratio with 1010 |
Antioxidant 1076 | Hindered Phenol | 2082-79-3 | 530.87 | White powder/granules | 50-55 | Soluble in oils, acetone | Low migration, complies with food contact standards | 0.05%-0.3% |
BHT | Synthetic Phenol | 128-37-0 | 220.35 | White powder | 69-72 | Soluble in oils, ethanol | Low cost, volatile (not suitable for high temps) | 0.01%-0.1% |
DLTDP | Thioester | 123-28-4 | 514.80 | White flakes/powder | 39-42 | Soluble in oils, acetone | Secondary antioxidant, provides sulfur for synergy | 0.1%-0.3% |
Antioxidant 626 | Phosphite | 26741-53-7 | 604.76 | White powder | 160-175 | Soluble in toluene, xylene | Hydrolysis-resistant, excellent high-temperature processing stability | 0.2%-0.5% |
Antioxidants inhibit oxidation reactions and delay material aging, widely used in the following fields:
Plastics: Prevent thermal oxidative degradation of polypropylene (PP), polyethylene (PE), polycarbonate (PC), etc., during processing or use, extending product lifespan.
Rubber: Delay oxidative aging during vulcanization of tires, seals, etc., avoiding hardening and cracking.
Synthetic Fibers: Protect nylon (PA) and polyester (PET) from molecular chain breakage during high-temperature spinning.
Lubricants: Inhibit oxidation of base oils to prevent acid and sludge formation, extending oil change intervals.
Fuels: Prevent oxidation-induced gum formation in gasoline and diesel during storage, avoiding engine system blockages.
Adhesives/Coatings: Prevent brittleness or discoloration caused by resin oxidation post-curing.
Elastomers: Maintain flexibility and strength of silicone, polyurethane, and similar materials.
Factors | Guidelines |
Material Type | 1.Polyolefins (PP/PE): Hindered phenol (1010) + phosphite (168) 2.Engineering plastics (PC/PET): Hydrolysis-resistant types (626) |
Process Conditions | 1.High-temperature processing (>200°C): Low-volatility antioxidants (e.g., 1010) 2.Outdoor exposure: Combine with UV stabilizers or metal deactivators |
Regulatory Compliance | 1.Food contact materials: FDA/EU 10/2011-certified antioxidants (e.g., 1076) 2.Environmental requirements: Avoid restricted components (e.g., BHT) |
Cost Efficiency | 1.Low-cost scenarios: BHT (note volatility and restrictions) 2.High-performance scenarios: Blended systems (1010+168+DLTDP) |
Polyolefins (PP/PE)
Recommended Antioxidants: 1010 (primary) + 168 (secondary), 1:1 ratio
Dosage: 0.1%-0.5% (by total weight)
Effect: Extends thermal aging resistance by 50%-200%.
Engineering Plastics (PC/PET)
Recommended Antioxidant: 626 (hydrolysis-resistant phosphite)
Dosage: 0.2%-0.5%
Effect: Prevents yellowing during processing and maintains transparency.
Rubber Products
Recommended Antioxidants: BHT (primary) + DLTDP (secondary)
Dosage: 0.05%-0.2%
Effect: Delays oxidative aging during vulcanization, reducing cracks.
Lubricants
Recommended Antioxidants: Amine-based (e.g., T501) + phenol-based (e.g., 1076)
Dosage: 0.1%-1.0%
Effect: Extends oil service life by 30%-50%.
Synergistic Effects: Combine primary/secondary antioxidants (e.g., 1010+168) for optimal performance.
Thermal Stability: Use low-volatility antioxidants (e.g., 1010) for high-temperature processing to minimize loss.
Migration Resistance: Select low-migration types (e.g., 1076) for food packaging.
Regulatory Compliance: Verify restrictions (e.g., BHT limitations in the EU).
Issue | Root Cause | Solution |
Yellowing of plastics | Oxidation-induced chromophores | Add phosphites (e.g., 168) to decompose peroxides |
Increased lubricant viscosity | Oxidation-generated sludge | Increase phenol antioxidant dosage (0.3%-1.0%) |
Surface cracking in rubber | Post-vulcanization oxidative aging | Blend BHT + DLTDP (0.1% + 0.1%) |
High-Efficiency Multifunctionality: Develop "all-in-one" additives with antioxidant, UV-resistant, and flame-retardant properties.
Green & Sustainable Solutions: Promote natural antioxidants (e.g., rosemary extract) and halogen/phosphorus-free formulations to comply with regulations like EU REACH.
High-Temperature Demand Growth: New energy vehicles and 5G electronics drive R&D for high-temperature-resistant antioxidants (>300°C, e.g., high-MW hindered phenols).
Optimized Compounding: Enhance synergy via molecular design (e.g., nano-encapsulation).
Plastic Replacement of Metals: Expanding use of engineering plastics in automotive and aerospace industries boosts antioxidant demand.
Stricter Environmental Regulations: Restrictions on traditional antioxidants (e.g., BHT) push adoption of eco-friendly alternatives.
Emerging Markets: Rapid industrialization in Asia-Pacific (China, India) positions the region as the largest consumer market.
Cost Pressure: High costs of natural antioxidants require scaling production for cost reduction.
Technical Barriers: Complex synthesis of high-temperature/hydrolysis-resistant antioxidants demands industry-academia collaboration.
Recycled Material Needs: Redesign antioxidant strategies for recycled plastics due to additive loss during reprocessing.
Bio-Based Antioxidants: Develop biodegradable antioxidants from plant extracts (e.g., green tea polyphenols).
Smart Manufacturing: Use AI algorithms to optimize antioxidant blends for customized solutions.
Extreme Environment Applications: Meet ultra-high stability requirements for deep-sea or aerospace materials.
Weifang Phoenix New Material Co., Ltd
Weifang Hota New Material Technology Co., Ltd. is a high-tech chemical enterprise integrating research and development, production, sales and technical services. Headquartered in Weifang, Shandong Province. Its production facilities are located in Weifang Binhai Chemical Industry Park, a state-approved chemical industry park.
Our mission is to be the leading sustainable "one-stop shop" chemical solutions company, providing customers with innovative, science-led, differentiated products and solutions. To this end, we provide a safe and healthy working environment for our employees and comply with all local, national and international regulations.
1.Q:How's the quality?
A:We are the source factory, quality is guaranteed.
2.Q:When does it ship?
A:We have standardized processes to ship as fast as possible.
3.Q:How do you protect the after-sales?
A:We keep samples of each batch and support returns and technical traceability in case of quality problems.